Capillary condensation of saturated vapor in a corner formed by two intersecting walls
نویسندگان
چکیده
The dynamics of saturated vapor between two intersecting walls is examined. It shown that, if the angle $\phi$ sufficiently small, becomes unstable, and spontaneous condensation occurs in corner, similar to so-called capillary into a porous medium. As result, an ever-growing liquid meniscus develops near corner. diffuse-interface model lubrication approximation are used demonstrate that grows only $\phi+2\theta<\pi$, where $\theta$ contact corresponding fluid/solid combination under consideration. This criterion has simple physical explanation: it holds, surface concave -- hence, Kelvin effect causes condensation. Once thickness condensate exceeds by order magnitude characteristic interfacial thickness, volume starts grow linearly with time. If near-vertex region corner smoothed, instability can be triggered off finite-size perturbations, such include enough cover smoothed aria microscopically-thin film.
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ژورنال
عنوان ژورنال: Physics of Fluids
سال: 2022
ISSN: ['1527-2435', '1089-7666', '1070-6631']
DOI: https://doi.org/10.1063/5.0095845